Structure Analysis 2
Code | Completion | Credits | Range |
---|---|---|---|
15NMR | Z,ZK | 3 | 2P+1C |
- Garant předmětu:
- Ján Kozempel, Martin Vlk
- Lecturer:
- Ján Kozempel, Martin Vlk
- Tutor:
- Ján Kozempel, Martin Vlk
- Supervisor:
- Department of Nuclear Chemistry
- Synopsis:
- Requirements:
-
Individual work of students based on interpretation spectral data examples of simple NMR spectra. Results will be evaluated by examination.
- Syllabus of lectures:
-
1. Principles of nuclear magnetic resonance. Magnetic properties of nuclei, resonance signal genesis, nuclear shielding and chemical shift, spin-spin interaction, relaxation mechanisms, NMR signal intensities.
2. NMR spectrometer - Basic components, types of construction, measurement techniques. Fourier transform Double resonance. Measurement of relaxation times. Solvent signal suppression.
3.Sample preparation, solvents, standards.
4. 1H-NMR techniques.
5. 13C-NMR techniques.
6. 15N, 18F, 31P, 2H, 3H and other measurement techniques.
7. Special NMR techniques. 2D-NMR (COSY, NOESY, TOCSY, HETCOR), solid-state NMR (MAS).
8. Interpretation of spectral data: 1H, 13C, 15N, 31P, special techniques 3H/2H
9. Interpretation and measurements of APT, DEPT, COESY, NOESY, TOCSY, HQMBC isotopic composition manifestations
10. Application of NMR.
- Syllabus of tutorials:
- Study Objective:
-
Acquired knowledge:
Students learn about generation of NMR signal, magnetic parameters of nuclei, spin-spin interaction, interpretation of spectral data in NMR.
Acquired skills:
The emphasis is put on correct evaluation of NMR spectra and identification of compounds.
- Study materials:
-
Key Literature:
1.Gunther H.: NMR Spectroscopy: Basic Principles, Concepts and Applications in Chemistry. Willey 2013.
Recommended Literature:
1.Williams D.H., Fleming I.: Spectroscopic methods in organic chemistry. 5th eddition.
- Note:
- Time-table for winter semester 2024/2025:
- Time-table is not available yet
- Time-table for summer semester 2024/2025:
- Time-table is not available yet
- The course is a part of the following study plans:
-
- Jaderná chemie (elective course)