Strukture Analysis 2
Code | Completion | Credits | Range |
---|---|---|---|
15STA2 | ZK | 2 | 2+0 |
- Course guarantor:
- Lecturer:
- Tutor:
- Supervisor:
- Department of Nuclear Chemistry
- Synopsis:
-
1.Basic principals of magnetic resonance, signal processing, shielding of nuclei, chemical shift, spin-spin interaction, relaxation, signals in NMR.
2.NMR spectrometer ? construction and function, basic techniques, Fourrier transformation, double-resonance, relaxation time measuremts, signal supresion,
3.Samples preparation, solvents, standards
4.1H-NMR techniques.
5.13C-NMR techniques.
6.Other techniques: 15N, 18F, 31P, 2H, 3H etc.
7.Specialities in NMR. 2D-NMR (COSY, NOESY, TOCSY, HECTOR), solid-state NMR (MAS)
8.Interpretation of spectral data: 1H, 13C, 15N, 31P, special techniques 3H/2H.
9.Interpretation and measurement APT, DEPT, COESY, NOESY, TOCSY, HQMBC ? isotopical modifications
10.Aplication of NMR.
- Requirements:
-
Individual work of students based on interpretation spectral data examples of simple NMR spectra. Results will be evaluated by examination.
- Syllabus of lectures:
-
1.Basic principals of magnetic resonance, signal processing, shielding of nuclei, chemical shift, spin-spin interaction, relaxation, signals in NMR.
2.NMR spectrometer ? construction and function, basic techniques, Fourrier transformation, double-resonance, relaxation time measuremts, signal supresion,
3.Samples preparation, solvents, standards
4.1H-NMR techniques.
5.13C-NMR techniques.
6.Other techniques: 15N, 18F, 31P, 2H, 3H etc.
7.Specialities in NMR. 2D-NMR (COSY, NOESY, TOCSY, HECTOR), solid-state NMR (MAS)
8.Interpretation of spectral data: 1H, 13C, 15N, 31P, special techniques 3H/2H.
9.Interpretation and measurement APT, DEPT, COESY, NOESY, TOCSY, HQMBC ? isotopical modifications
10.Aplication of NMR.
- Syllabus of tutorials:
- Study Objective:
-
Acquired knowledge:
Students learn about generation of NMR signal, magnetic parameters of nuclei, spin-spin interaction, interpretation of spectral data in NMR.
Acquired skills:
The emphasis is put on correct evaluation of NMR spectra and identification of compounds.
- Study materials:
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Compulsory literature:
1.Böhm S., Smrčková S.: Strukturní analýza organických sloučenin, VŠCHT, 1995.
2.Kováč Š. a kol.: Spektrálne metódy v organickej chémii. Bratislava Alfa 1980.
3.Gunther H.: NMR Spectroscopy: Basic Principles, Concepts and Applications in Chemistry. Willey 2013.
Optional literature:
Williams D.H., Fleming I.: Spectroscopic methods in organic chemistry. 5. vydání.
- Note:
- Further information:
- No time-table has been prepared for this course
- The course is a part of the following study plans: