Physical Chemistry 1
Code | Completion | Credits | Range |
---|---|---|---|
15FCHN1 | Z,ZK | 5 | 3+2 |
- Course guarantor:
- Jan Bárta, Viliam Múčka
- Lecturer:
- Viliam Múčka
- Tutor:
- Jan Bárta
- Supervisor:
- Department of Nuclear Chemistry
- Synopsis:
-
The introductive part is devoted to the recapitulation of the thermodynamic systems and thermodynamic properties of ideal and real gases. Next chapters are devoted to the first, second and third law of thermodynamics and their applications. Last but not least, attention is devoted also to the thermodynamic, phase and chemical equilibriums as well as to the elementals of nonequilibrium thermodynamics.
- Requirements:
-
Differential and integral calculus, general chemistry
- Syllabus of lectures:
-
1.Recapitulation of describing of ideal and real gases and the zero law of thermodynamics
2.The first law of thermodynamics and the reaction heats
3.The second law of thermodynamics
4.The third law of thermodynamics
5.Thermodynamic equilibrium
6.One component phase equilibrium
7.Ideal and non ideal solutions
8.Phase diagrams for the two- and three- component systems
9.Reaction equilibrium
10.The equilibrium constant and degree of conversion
11.Degree of conversion
12.Nonequilibrium thermodynamics
- Syllabus of tutorials:
-
1.Thermodynamic fundamentals
2.Ideal and real gases
3.First thermodynamic law, calculation of heat capacities and volume work of the systems
4.Calculatio of heats of chemical reactions and heats of phase transitions, termochemistry
5.Second thermodynamic law, dependence of thermodynamic functions on
thermodynamic variables
6.Thermodynamic equilibrium
7.Calculation of fugacity and aktivity of real systems.
8.Chemical equilibrium.
9.Determination of the equilibrium constant and its temperature dependence.
10.Reaction isotherm.
11.Calculation of equilibrium constant from thermodynamic data.
12.Effects of equilibrium conditions on the chemical equilibrium.
- Study Objective:
-
To acquire the knowledge of principles of phenomenologic thermodynamics (thermodynamic laws, thermodynamic, phase and chemical equilibrium, elementals of nonequilibrium thermodynamics) and the competence of their applications is the goal of study.
- Study materials:
-
Key references:
1. Atkins P., de Paula J.: Physical Chemistry, seventh edition. Oxford University
press, Oxford, New York 2002.
2. Levine I. N.: Physical Chemistry, 3th edition, McGraw-Hill Boock Company.
Recommended references:
1. Zumdahl, S.: Chemical principles, fifth edition, Houghton Mifflin Company,
Boston, NewYork, 2005
2.Chang, R.: Chemistry, ninth edition, McGraw-Hill, New York, 2007
3.Murphy B.,Murphy C., Hathaway B.: Physical Chemistry Calculation, Royal Society of Chemistry, 1997
- Note:
- Time-table for winter semester 2024/2025:
-
06:00–08:0008:00–10:0010:00–12:0012:00–14:0014:00–16:0016:00–18:0018:00–20:0020:00–22:0022:00–24:00
Mon Tue Wed Thu Fri - Time-table for summer semester 2024/2025:
- Time-table is not available yet
- The course is a part of the following study plans:
-
- Jaderná chemie (compulsory course in the program)
- Vyřazování jaderných zařízení z provozu (compulsory course in the program)