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CZECH TECHNICAL UNIVERSITY IN PRAGUE
STUDY PLANS
2023/2024

Physical chemistry

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Code Completion Credits Range Language
2182001 KZ 4 2P+1C Czech
Garant předmětu:
Radek Šulc
Lecturer:
Jaromír Štancl
Tutor:
Jaromír Štancl
Supervisor:
Department of Process Engineering
Synopsis:

Basic principles of physical chemistry in the field assuming real behavior especially that are demonstrated on technical applications. Volumetric properties of fluids. Thermodynamic properties of fluids. Phase equilibria. Solution Thermodynamics. Thermochemistry. Chemical reaction equilibrium.

Requirements:

Calculation of examples.

Syllabus of lectures:

1. Introduction. Concentration.

2. PVT behaviour of fluids: real gases, cubic equations of state.

3. PVT behaviour of fluids: generalised correlations for gases and liquids.

4. Basic principles of thermodynamics (the first and second law of thermodynamics).

5. Chemical thermodynamics.

6. Thermodynamic properties of fluids.

7. Fugacity and fugacity coefficient.

8. Solution thermodynamics.

9. Phase equilibria of one-component systems

10. Phase equilibria of multi-component systems.

11. Vapor - liquid equilibrium.

12. Systems with chemical reaction: Mass balances.

13. Systems with chemical reaction: Thermochemistry. Energy balances.

14. Systems with chemical reaction: Chemical reaction equilibrium.

Syllabus of tutorials:

1. Concentration

2. PVT behaviour of pure fluids: cubic equations of state.

3. PVT behaviour of pure fluids: generalised correlations.

4. PVT behaviour of fluids: fluid mixtures.

5. Thermodynamic properties of fluids: residual properties.

6. Thermodynamic properties of fluids: application (isobaric heating, adiabatic expansion, Joule-Thompson effect).

7. Fugacity and fugacity coefficient.

8. Solution thermodynamics.

9. Phase equilibria of one-component systems (vapor pressure, vaporization enthalpy)

10. Vapor - liquid equilibrium: ideal behaviour.

11. Vapor - liquid equilibrium: real behaviour.

12. Systems with chemical reaction: Mass balances.

13. Systems with chemical reaction: Thermochemistry. Energy balances.

14. Systems with chemical reaction: Chemical reaction equilibrium.

Study Objective:
Study materials:

Smith JM, Van Ness H.C, Abbot M. : Introduction to Chemical Engineering Thermodynamics. McGraw Hill, 2000

Moore W.: Fyzikální chemie. SNTL 1979

Russell J.B.: General chemistry, McGraw Hill, 1992

Note:
Time-table for winter semester 2023/2024:
06:00–08:0008:00–10:0010:00–12:0012:00–14:0014:00–16:0016:00–18:0018:00–20:0020:00–22:0022:00–24:00
Mon
Tue
roomT4:C2-434
Štancl J.
14:15–15:45
(lecture parallel1)
Dejvice
Posluchárna 434
roomT4:C2-434
Štancl J.
16:00–16:45
(lecture parallel1
parallel nr.101)

Dejvice
Posluchárna 434
Wed
Thu
Fri
Time-table for summer semester 2023/2024:
Time-table is not available yet
The course is a part of the following study plans:
Data valid to 2024-07-13
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