Physical Chemistry

Garant předmětu:

Lecturer:

Tutor:

Supervisor:

Department of Process Engineering

Synopsis:

Basic principles of physical chemistry in the field assuming real behavior especially that are demonstrated on technical applications. Volumetric properties of fluids. Thermodynamic properties of fluids. Phase equilibria. Solution Thermodynamics. Thermochemistry. Chemical reaction equilibrium.

Requirements:

Calculation of examples.

Syllabus of lectures:

1. Introduction. Concentration.

2. PVT behaviour of fluids: real gases, cubic equations of state.

3. PVT behaviour of fluids: generalised correlations for gases and liquids.

4. Basic principles of thermodynamics (the first and second law of thermodynamics).

5. Chemical thermodynamics.

6. Thermodynamic properties of fluids.

7. Fugacity and fugacity coefficient.

8. Solution thermodynamics.

9. Phase equilibria of one-component systems

10. Phase equilibria of multi-component systems.

11. Vapor - liquid equilibrium.

12. Systems with chemical reaction: Mass balances.

13. Systems with chemical reaction: Thermochemistry. Energy balances.

14. Systems with chemical reaction: Chemical reaction equilibrium.

Syllabus of tutorials:

1. Concentration

2. PVT behaviour of pure fluids: cubic equations of state.

3. PVT behaviour of pure fluids: generalised correlations.

4. PVT behaviour of fluids: fluid mixtures.

5. Thermodynamic properties of fluids: residual properties.

6. Thermodynamic properties of fluids: application (isobaric heating, adiabatic expansion, Joule-Thompson effect).

7. Fugacity and fugacity coefficient.

8. Solution thermodynamics.

9. Phase equilibria of one-component systems (vapor pressure, vaporization enthalpy)

10. Vapor - liquid equilibrium: ideal behaviour.

11. Vapor - liquid equilibrium: real behaviour.

12. Systems with chemical reaction: Mass balances.

13. Systems with chemical reaction: Thermochemistry. Energy balances.

14. Systems with chemical reaction: Chemical reaction equilibrium.

Study Objective:

Study materials:

Smith JM, Van Ness H.C, Abbot M. : Introduction to Chemical Engineering Thermodynamics. McGraw Hill, 2000

Moore W.: Fyzikální chemie. SNTL 1979

Russell J.B.: General chemistry, McGraw Hill, 1992

Note:

Further information:

No time-table has been prepared for this course

The course is a part of the following study plans: