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CZECH TECHNICAL UNIVERSITY IN PRAGUE
STUDY PLANS
2019/2020

Strukture Analysis 2

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Code Completion Credits Range
15STA2 ZK 2 2+0
Lecturer:
Martin Vlk, Ján Kozempel (guarantor)
Tutor:
Supervisor:
Department of Nuclear Chemistry
Synopsis:

1.Basic principals of magnetic resonance, signal processing, shielding of nuclei, chemical shift, spin-spin interaction, relaxation, signals in NMR.

2.NMR spectrometer ? construction and function, basic techniques, Fourrier transformation, double-resonance, relaxation time measuremts, signal supresion,

3.Samples preparation, solvents, standards

4.1H-NMR techniques.

5.13C-NMR techniques.

6.Other techniques: 15N, 18F, 31P, 2H, 3H etc.

7.Specialities in NMR. 2D-NMR (COSY, NOESY, TOCSY, HECTOR), solid-state NMR (MAS)

8.Interpretation of spectral data: 1H, 13C, 15N, 31P, special techniques 3H/2H.

9.Interpretation and measurement APT, DEPT, COESY, NOESY, TOCSY, HQMBC ? isotopical modifications

10.Aplication of NMR.

Requirements:

Individual work of students based on interpretation spectral data examples of simple NMR spectra. Results will be evaluated by examination.

Syllabus of lectures:

1.Basic principals of magnetic resonance, signal processing, shielding of nuclei, chemical shift, spin-spin interaction, relaxation, signals in NMR.

2.NMR spectrometer ? construction and function, basic techniques, Fourrier transformation, double-resonance, relaxation time measuremts, signal supresion,

3.Samples preparation, solvents, standards

4.1H-NMR techniques.

5.13C-NMR techniques.

6.Other techniques: 15N, 18F, 31P, 2H, 3H etc.

7.Specialities in NMR. 2D-NMR (COSY, NOESY, TOCSY, HECTOR), solid-state NMR (MAS)

8.Interpretation of spectral data: 1H, 13C, 15N, 31P, special techniques 3H/2H.

9.Interpretation and measurement APT, DEPT, COESY, NOESY, TOCSY, HQMBC ? isotopical modifications

10.Aplication of NMR.

Syllabus of tutorials:
Study Objective:

Acquired knowledge:

Students learn about generation of NMR signal, magnetic parameters of nuclei, spin-spin interaction, interpretation of spectral data in NMR.

Acquired skills:

The emphasis is put on correct evaluation of NMR spectra and identification of compounds.

Study materials:

Compulsory literature:

1.Böhm S., Smrčková S.: Strukturní analýza organických sloučenin, VŠCHT, 1995.

2.Kováč Š. a kol.: Spektrálne metódy v organickej chémii. Bratislava Alfa 1980.

3.Gunther H.: NMR Spectroscopy: Basic Principles, Concepts and Applications in Chemistry. Willey 2013.

Optional literature:

Williams D.H., Fleming I.: Spectroscopic methods in organic chemistry. 5. vydání.

Note:
Time-table for winter semester 2019/2020:
Time-table is not available yet
Time-table for summer semester 2019/2020:
Time-table is not available yet
The course is a part of the following study plans:
Data valid to 2019-10-18
For updated information see http://bilakniha.cvut.cz/en/predmet4997206.html